PENGARUH MATERIAL COUNTER ELECTRODE PADA DYE-SENSITIZED SOLAR CELL

Natalita Maulani Nursam

Abstract

Sel surya tersensitasi pewarna atau dye-sensitized solar cell (DSSC) merupakan sel surya generasi ketiga yang teknologinya sangat menjanjikan untuk  untuk menjadi alternatif sel surya berbasis silikon. DSSC umumnya memiliki dua bagian utama, yaitu working electrode (anoda) dan counter electrode (katoda). Counter electrode memiliki peran krusial pada DSSC, utamanya sebagai katalis untuk mempercepat reaksi reduksi-oksidasi pada elektrolit. Dengan demikian, pemilihan jenis material pada bagian counter electrode memiliki pengaruh signifikan terhadap performa DSSC secara keseluruhan. Platina merupakan salah satu material yang sangat umum digunakan pada counter electrode DSSC dikarenakan karakteristiknya yang hampir mendekati counter electrode ideal. Material counter electrode lain seperti karbon dan poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) juga digunakan sebagai alternatif counter electrode platina yang memiliki harga yang mahal dan persediaan terbatas. Dalam paper review ini akan dibahas mengenai berbagai usaha yang dilakukan untuk meningkatkan performa DSSC menggunakan counter electrode platina, karbon dan PEDOT:PSS. Usaha tersebut meliputi peningkatan aktivitas katalis, konduktivitas, porositas, dan luas permukaan counter electrode. Beberapa penelitian telah membuktikan bahwa karbon dan PEDOT:PSS mampu menghasilkan performa DSSC yang mendekati dan bahkan melebihi counter electrode platina. Pengaruh variasi metode deposisi dan jenis komponen lain seperti fotoanoda, dye, dan elektrolit terhadap performa DSSC dengan counter electrode platina, karbon dan PEDOT:PSS juga dibahas dalam paper ini. Pemilihan material dan komponen DSSC yang sesuai, sangat penting dilakukan untuk menghasilkan sel surya dengan performa tinggi.

Full Text:

PDF

References

B. O’Regan dan M. Gätzel, “A Low Cost, High Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Films,” Nature, vol. 353, pp. 737-740, 1991.

D. Wei, “Review: Dye-Sensitized Solar Cells,” Int. J. Mol. Sci., vol. 11, issue 3, pp. 1103-1113, 2010.

M. Chen dan L. L. Shao, “Review on the Recent Progress of carbon Counter Electrode for Dye-Sensitized Solar Cells,” Chem. Eng. J., vol. 304, pp. 629-645, 2016.

K. Kakiage, Y. Aoyama, T. Yano, K. Oya, J. I. Fujisawa, dan M. Hanaya. “Highly Efficient Dye-Sensnitized Solar Cells with Collaborative Sensitization by Silyl-anchor and Carboxy-anchor Dyes,” Chem. Com., pp. 1-4, 2015.

N. Papageorgiou dan M. Grätzel, “An Iodine/ Triiodide Reduction Electrocatalyst for Aqueous and Organic Media,” J. Electrochem. Soc., vol. 248, issues 13-14, pp. 1421-1446, 2004.

J. H. Wu, Z. Lan, J. M. Lin, M. L. Huang, Y. F. Huang, L. Q. Fan, G. G. Luo, Y. Lin, Y. M. Xie, dan Y. L. Wei, “Counter Electrodes in Dye-Sensitized Solar Cells,” Chem. Soc. Rev., vol. 46. pp. 5975-6023, 2017.

S. Thomas, T. G. Deepak, G. S. Anjusree, T. A. Arun, S. V. Nair, dan A. S. Nair, “A Review on Counter Electrode Materials in Dye-Sensitized Solar Cells,” J. Mater. Chem. A., vol. 2, pp. 4474-4490, 2014.

L. Giribabu, R. K. Kanaparthi, dan V. Velkannan, “Molecular Engineering of Sensitizers for Dye-Sensitized Solar Cell Applications,” Chem. Rec., vol. 12, issue 3, pp. 306-328, 2012.

N. M. Nursam, P. N. Anggraini, Shobih, dan J. Hidayat, “Low-Cost Monolithic Dye-Sensitized Solar Cells Fabricated on Single Conductive Substrate,” Internasional Conference on Radar, Antenna, Microwave, Electronics, and Telecomunications, pp. 164-168, 2017.

J. Gong, J. Liang, dan K. Sumathy, “Review on Dye-Sensitized Solar Cells: Fundamental Concepts and Novel Material,” Renew. Sust. Energ. Rev., vol. 16, pp. 5848-5860, 2012.

A. Andualem dan S. Demis, “Review on Dye-Sensitized Solar Cells (DSSC),” Edelweis Applied Science and technology, issue 2, pp. 145-150. 2018.

M. X. Wu dan T. L. Ma, “Recent Progress of Counter Electrode Catalysts in Dye-Sensitized Solar Cells,” J. Phys. Chem., vol. 118, issue 30, pp. 16727-16742, 2014.

Y. J. Zhu, H. Y. Gue, H. K. Zheng, Y. N. Lin, C. J. Gao, Q. J. Han, dan M. X. Wu, “Choose a Reasonable Counter Electrode Catalyst Toward a Fixed Redox Couple in Dye Sensitized Solar Cells,” Nano Energy, vol. 21, pp. 1-18, 2016.

Y. L. Lee, C. L. Chen, L. W. Chong, C. H. Chen, Y. F. Liu, dan C. F. Chi, “A Platinum Counter Electrode with High Electrochemical Activity and High Transparency for Dye-Sensitized Solar Cells,” Electrochem. Commun., vol. 12, pp. 1662-1665, 2010.

M. K. Nazeeruddin, A. Kay, I. Rodicio, H. Baker, E. Muller, P. Liska, N. Vlachopoulos, dan M. Grätzel, “Conversion of Light to Electricity by cis-X2Bis(2,2’-bipyridyl-4,4’-dicarboxylate)ruthenium(II) Charge-Transfer Sensitizer (Z=Cl-, Br, I-, CN-, and SCN-) on Nanocrystalline TiO2 Electrodes,” J. AM. Chem. Soc., vol. 115, pp. 6382-6390, 1993.

N. Papageorgiou dan M. Grätzel, “An Iodine/ Triiodide Reduction Electrocatalyst for Aqueous and Organic Media,” J. Electrochem. Soc., vol. 144, issue 3, pp. 876-884, 1997.

Y. L. Lee, C. L. Chen, L. W. Chong, C. H. Chen, Y. F. Liu, dan C. F. Chi, “A Platinum Counter ELectrode with High Elecctrochemical Activity and High Transparency for Dye-Sensitized Solar Cells,” Electrochem. Commun., vol. 12, pp. 1662-1665, 2010.

J. L. Lan, T. C. Wei, S. P. Wa, dan G. Z. Cao, “Effects of Iodine Content in the Electrolyte on the Charge Transfer and Power Conversion Efficiency of Dye-Sensitized Solar Cells Under Low Light Intensities,” J. Phys. Chem., vol. 116, issue 49, pp. 25727-25733, 2012.

A. Iefanova, U. Gautam, P. Pudel, D. Davoux, J. Nepal, V. Mallam, Q. Qiao, Louge, dan M. F. Baroughi, “Low Cost Platinum Counter Electrode for Dye-Sensitized Solar Cells,” IEEE 39 Photovoltaic Specialists Conference (PVSC), 2013.

X. M. Fang, T. L. Ma, G. Q. Guan, M. Akiyama, T. Kida, dan E. Abe, “Effect of the Thickness of the PT Film Coated on Counter Electrode on the Performance of a Dye-Sensitized Solar Cell,” J. Electroanal. Chem.,vol. 570, pp. 257-263, 2014.

I. C. Chen, Y. H. Wei, M. C. Tsai, F. G. Tseng, S. Y. Wei, H. C. Wu, dan C. K. Hsieh, “Performance of Dye-Sensitized Solar Cells Based on Platinum Nanoroses Counter Electrode,” Surf. Coat, Tech.,vol. 320, pp. 409-413, 2017.

M. X. Wu, X. Lin, T. H. Wang, J. S. Qiu, dan T. L. Ma, “Low Cost Dye-Sensitized Solar Cell based on Nine Kinds Electrodes,” Energ. Environ. Sci., vol. 4, pp. 2308-2315, 2011.

A. Yella, H. W. Lee, H. N. Tsao, C. Y. Yi, A. K. Chandiran, M. K. Nazeeruddin, E. W. G. Diau, C. Y. Yeh, S. M. Zakeeruddin, dan M. Grätzel, “Porphyrin-Sensitized Solar Cells with Cobalt (II/III)-Based Redox Electrolyte Exceed 12 Percent Efficiency,” Science, vol.334, issue 6056, pp. 629-634, 2011.

H. Han, u. Bach, Y. Cheng, R. A. Caruso, dan C. Macrae, “Design for Monolithic All Solid State Dye-Sensitized Solar Cells with a Platinized Carbon Counter Electrode,” Appl. Phys. Lett., vol. 94, pp. 103102, 2009.

K. Skupien, P. Putyra, J. Walter, R. H. Kozlowski, G. Khelashvili, A. Hinch, dan U. Würfel, “Catalytic Materials Manufactured by the Polyol Process for Monolithic Dye Sensitized Solar Cells,” Progress in Photovoltaic: Research and Applications, vol. 17, issue 1, pp. 67-73. 2009.

Y. G. Rong, Z. L. Ku, M. Xu, G. H. Liu, H. Wang, dan H. W. Han, “Monolithic All Solid State Dye-Sensitized Solar Cells,” Fron. Optoelectron., vol. 6, issue 4, pp. 357-372. 2013.

N. M. Nursam, A. Istiqomah, J. Hidayat, P. Anggraini, dan Shobih, “Analysis of Catalytic Material Effect on the Photovoltaic Properties of Monolithic Dye-Sensitized Solar Cells,” Jurnal Elektronika dan telekomunikasi, vol. 17, issue 2, pp. 30-35. 2017.

E. Olsen, G. Hagen, dan S. E. Lindquist, “Dissolution of Platinum in Methoxy Propionitrile Containing Lil/I2,” Sol. Energ. Mat. Sol. C., vol. 63, pp. 367-373. 2000.

A. Kay dan M. Grätzel, “Low Cost Photovoltaic Modules Based on Dye Sensitized Nanocrystalline Titanium Dioxide and Carbon Powder,” Sol. Energ, Mat. Sol. C., vol. 114, pp. 99-117, 1996.

K. Xia, Q, Gao, J. Jiang, dan J. Hu, “Hierarchical Porous Carbons with Controlled Micropores and Mesopores for Supercapacitor Electrode materials,” Carbon, vol. 46, issue 13, pp. 1718-1726, 2008.

S. J. Peng, F. Y. Cheng, J. F. Shi, Z. L. Tao, dan J. Chen, “High Surface Area Microporous Carbon as the Efficient Photocathode of Dye-Sensitized Solar Cells,” Solid State Sci., vol. 11, issue 12, pp. 2051-2055. 2009.

H. W. Wu, Z. B. Lv, Z. Z. Chu, D. Wang, S. C. Hou, dan D. C. Zou, “Graphite and Platinum’s Catalytic Selectivity for Disulfide/Thiolate (T2/T-) and triiodide /Iodide (I3 /I-),” J. Mater. Chem, vol. 21, pp. 14815-14820, 2011.

E. Ramasamy, W. J. Lee, D. Y. Lee, dan J. S. Song, “Nanocarbon Counter Electrode for Dye Sensitized Solar Cells,” Appl. Phys. Let., vol. 90, pp. 173103, 2007.

P. Joshi, Y. Xie, M. Ropp, D. Galipeau, S. Bailey, dan Q. Q. Qiao, “Dye-Sensitized Solar Cells Based on Low Cost Nanoscale Carbon/TiO2 Composite Counter Electrode,” Energ. Environ. Sci., vol. 2, pp. 426-429. 2009.

K. Imoto, K. Takahashi, T. Yamaguchi, T. Komura, J. I. Nakamura, dan K. Murata, “High Performance Carbon Counter Electrode for Dye Sensitized Solar Cells,” Sol. Energ. Mat. Sol. C., vol. 79, pp. 459-469. 2003.

C. H. Yoon, S. K. Chul, H. H. Ko, S. Yi, dan S. H. Jeong, “Enhanced Performance of Dye-Sensitized Solar Cells with Activated Carbons.” J. Nanosci. Nanoteknologi, vol. 13, issue 12, pp. 7875-7879, 2013.

A. A. Arbab, K. C. Sun, I. A. Sahito, M. B. Qadir, Y. S. Choi, dan S. H. Jeong, “A Novel Activated-Charcoal Doped Multiwalled Carbon nanotube Hybrid for Quasi Solid State Dye-Sensitized Solar Cell Outperforming PT Electrode,” ACS. Appl. Mater. Interfaces., vol. 8, Pp. 7471-7482, 2016.

Y. Wang, H. G. Wei, Y. Lu, S. Y. Wei, E. K. Wujcik, dan Z. H. Gui, “Multifunctional Carbon Nanostructures for Advances Energy Storage Applications,” Nanomaterials, vol. 5, pp. 755-777, 2015.

R.H. Lee,Y. W. Chang, J. C. Hwang, Y. C. Chen, dan R. J. Jeng, “Electrochemical Impedance Characterization and Photovoltaic Performance of N719 Dye-Sensitized Solar Cells Using Quaternizaed Ammonium Iodide Containing Polyfluorene Electrolyte Solutions,” Polym. Adv. Technol., vol. 22, issue 12, pp. 1650-1657.

S. W. Lee dan K. S. Ahn, “Effect of TiCl4 Treatment of Nanoporous TiO2 Film on Morphology Ligh Harvesting and Charge Carrier Dynamics in Dye Sensitized Solar Cells,” J. Phys. Chem., vol. 116, pp. 21285-21290, 2012.

A. A. Arbab, N. Mengal, I. A. Sahito, A. A. Memon, dan S. H. Jeong, “An Oeganic Route for the Synthesis of Cationic Porous Graphite Nanomaterial Used as Photocatalyst and Electrocatalyst for Dye-Sensitized Solar Cell,” Electrochim. Acta., vol. 266, pp. 43-53, 2018.

Q. Liu, Y. Zhou, Y. Duan, M. Wang, dan Y. Lin, “Improved Photovoltaic Performance of Dye-Sensitized Solar Cells (DSSCs) by Zn + Mg Co-Doped TiO2 Electrode,” Electrochim. Acta.,vol. 95, pp. 48-53, 2013.

G. Veerappan, K. Bojan, dan S. W. Rhee, “Sub-micrometer-sized Graphite as a Conducting and catalytic Counter Electrode for Dye-Sensitized Solar Cells,” ACS Appl. Mater. Interfaces, vol. 3, issue 3, pp. 857-862, 2011.

S. Ito dan K. Takahashi, “Fabrication of Monolithic Dye-Sensitized Solar Cell Using Ionic Liquid Electrolyte,” J. Photoenergy, pp. 1-6, 2012.

F. Arif, N. M. Nursam, N. Prastomo, dan Shobih, “Influence of Carbon Counter Electrode Composition on the Performance of Monolithic Dye-Sensitized Solar Cells,” J. Phys: Conference Series, vol. 1191, series 1, pp. 012021, 2019.

Y. Saito, Kitamura, T, Y. Wada, dan S. Yanagida, “Poly (3,4-ethylenedioxythio-phene) as a Hole COnductor in Solid State Dye-Sensitized Solar Cells,” Synth. Met. Vol. 131, pp. 185-187, 2002.

H. Ellis, N. Vlachopoulos, L. Haggman, C. Perruchot, M. Jouini, G. Boschloo, dan A. Hagfeldt, “PEDOT Counter Electrodes for Dye Sensitized Solar Cells Prepared by Aqueous Micellar Electrodeposition,” Electrochim. Acta., vol. 107, pp. 45-51, 2013.

H. N. Tsao, J. Burschka, C. Y. Yi, F. Kessler, M. K. Nazeeruddin, dan M. Grätzel, “Influence of the Interfacial Charge Transfer Resistance at the Counter Electrode in Dye Sensitized Solar Cells Employing Cobalt Redox Shuttle,” Energ. Environ. Sci., vol. 4, pp. 4921-4924, 2011.

J. Burschka, V. Brault, S. Ahmad, L. Breau, M. K. Nazeeruddin, B. Marsan, S. M. Zakeeruddin, dan M. Grätzel, “Influence of the Counter Electrode on the Photovoltaic Performance of Dye-Sensitized Solar Cells Using a Disulfide/Thiolate Redox Electrolyte,” Energ. Environ. Sci, vol. 5, pp. 6089-6097, 2011.

F. Jonas, W. Krafft, dan B. Muys, “Poly(3, 4-ethylenedioxythiophene Conductive Coatings, Technical Applications and Properties,” Macromol. Symp., vol. 100, issue 1, pp. 169-173, 1995.

S. Kirchmeyer dan K. Reuter, “Scientific Importance Properties and Growing Applications of Poly(3,4-ethylenedioxythiophene),” J. Mater. Chem., vol. 15, issue 21, pp. 2077-2088, 2005.

F. Zhang, M. johansson, M. R. Andersson, J. C. Hummelen, dan O. Inqana, “Polymer Photovoltaic Cells with Conducting Polymer Anodes,” J. Adv. Mater.,vol. 14, issue 9, pp. 662-665, 2002.

J. G. Chen, H. Y. Wei, dan K. Ho, “Using Modified Poly(3,4-ethylenedioxythiophene): Poly(Styrene Sulfonate) Film as a Counter Electrode in Dye-Sensitized Solar Cell,” Sol. Energ. Mater. Sol. C., vol. 91, issue 91, pp. 1472-1477, 2007.

D. Song, M. Li, F. Bai, Y. Li, Y. Jiang, dan B. Jiang, “Silicon Nanoparticles/ PEDOT:PSS Nanocomposite as an Efficient Counter Electrode for Dye-Sensitized Solar Cells,” Funct. Mater. Lett., vol. 6, issue 4, pp. 1350048, 2013.

S. Edalati, A. Houshangi, N. Torabi, Z. Baneshi, dan Z. Behjat, “Heuristic Method of Fabricating Counter Electrodes in Dye-Sensitized Solar Cells Based on a PEDOT:PSS Layer as a Catalytic Material,” J. Phys. D. Appl. Phys., vol. 50, pp. 065501, 2016.

Y. K. Kim, S. H. Park, W. P. Hwang, M. H. Seo, H. W. Park, Y. W. Jang, M. R. Kim, dan J. K. Lee, “Impedance SPectroscopy on Dye Sensitized Solar Cells with a Poly(Ethylenedioxythiophene): Poly(Styrene sulfonate) Counter Electrode,” J. Korean Phys. Soc., vol. 60, issue 20, pp. 2049-2053, 2011.

D. J. Yun, H. Ra, dan S. W. Rhee, “Concentration Effect on Multiwalled Carbon Nanotube and Poly(3,4-ethylenedioxythiophene) Polymerized with Poly(4-Styrenesulfonate) Conjugated Film on the Catalytic Activity for Counter Electrode in Dye-Sensitized Solar Cells,” Renewable Energy, vol. 50, pp. 692-700, 2012.

G. T. Yue, J. H. Wu, Y. M. Xiao, J. M. Lin, dan M. L. Huang, ”Dye Sensitized Solar Cell Based on PEDOT:PSS Counter Electrode,” Chinese. Sci. Bul., vol. 58, issue 4-5, pp. 559-566, 2013.

S. J. Thompson, J. M. Pringle, X. L. Zhang, dan Y. B. Cheng, “A Novel Carbon PEDOT Composite COunter Electrode for Monolithic Dye Sensitized Solar Cells,” J. Phys. Chem. C., vol 114, pp. 2365-2369, 2010.

J. Kwon, N. G. Park, J. Y. Lee, M. J. Ko, dan J. H. Park, “Highly efficient Monolithic Dye Sensitized Solar Cells. ACS Apl. Mater. Interfaces, vol 5, issue 6, pp. 2070-2074, 2013.

K. K. Putra, E. S. Rosa, dan N. Prastomo, “Development of Monolithic Dye-Sensitized Solar Cell Fabrication with Polymer Based Counter Electrode,” J. Phys: Conference Series, pp. Vol. 1191, issue 1, pp. 012029, 2019.

Copyright (c) 2020 Metalurgi
Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

Refbacks

  • There are currently no refbacks.