Pengaruh Penambahan Inhibitor Ekstrak Tembakau Terhadap Laju Korosi Internal Pipa API 5L X-52 Pada Artificial Brine Water Dengan Injeksi Gas CO2 [Effect of Addition of Extracted Tobacco Inhibitor to The Corrosion Rate of Internal Steel Pipe API 5L X-52 in Artificial Brine Water With CO2 Gas Injection]

Rapli Nur Ahmadi, Soesaptri Oediyani, Gadang Priyotomo

Abstract

Crude oil containing brine water with high concentration of NaCl and HCO3 and the presence of dissolved CO2 gas may increase the potential for corrosion in the pipeline. The use of natural corrosion inhibitor is one of the alternative to solve these problem. Natural materials were chosen as an alternative because it is safe, readily available, biodegradable, low cost, and environmentally friendly. This study was conducted to determine the effect of tobacco extracts on the rate of corrosion and inhibition efficiency. The novelty of this research is a continuous injection of CO2 gas that does not exist in previous research. Spectroscopy analysis was conducted to determine the chemical composition of samples of steel API 5L X-52, TLC densitometry was used to determine the levels of nicotine in tobacco sauce. Gamry Potensiostat Type 6:25 was used for testing the corrosion behavior, using the Tafel polarization and EIS methods. The results show that, the corrosion rate of samples decreased with the addition of tobacco extracts. The addition of 60 ppm of tobacco extract in a solution decrease corrosion rate samples at 8.95 mpy in ABW 1 and 9.87 mpy in ABW 2. Optimum inhibition efficiency occurs upon the addition of 60 ppm tobacco extracts, for the solution of ABW 1 by 79.51% and amounted to 80.94% ABW 2. The inhibition efficiency began to decline by the addition of 80 ppm, to 42.32% in ABW 1 by and 68.71% in ABW 2.

Abstrak

Crude oil yang mengandung brine water dengan kadar NaCl dan HCO3 - yang tinggi serta adanya gas CO2 yang terlarut dapat meningkatkan potensi korosi pada pipa. Penggunaan inhibitor korosi alami menjadi alternatif baru untuk menyelesaikan masalah tersebut. Bahan alam dipilih sebagai alternatif karena bersifat aman, mudah didapatkan, bersifat biodegradable, biaya murah, dan ramah lingkungan. Penelitian ini dilakukan untuk mengetahui pengaruh penambahan ekstrak tembakau terhadap laju korosi dan efisiensi inhibisi yang dihasilkan dengan menambahkan pembaharuan penelitian berupa penginjeksian gas CO2 secara kontinu yang belum ada pada penelitian sebelumnya. Pengujian pada penelitian ini menggunakan spectroscopy untuk mengetahui komposisi kimia sampel baja API 5L X-52, TLC. Densitometri digunakan untuk mengetahui kadar nikotin pada sampel tembakau. Gamry Potensiostat Type 6.25 digunakan untuk pengujian polarisasi Tafel dan EIS. Hasil penelitian menunjukkan bahwa data laju korosi baja API 5L X-52 mengalami penurunan dengan penambahan ekstrak tembakau. Penurunan optimum laju korosi terjadi pada penambahan 60 ppm ekstrak tembakau pada larutan ABW 1 sebesar 8,95 mpy dan ABW 2 sebesar 9,87 mpy. Peningkatan optimum efisiensi inhibisi terjadi pada penambahan 60 ppm ekstrak tembakau, untuk larutan ABW 1 sebesar 79,51% dan ABW 2 sebesar 80,94%. Efisiensi inhibisi mulai mengalami penurunan kembali pada penambahan 80 ppm, untuk larutan ABW 1 sebesar 42,32% dan ABW 2 sebesar 68,71%.

 

Keywords

Baja API 5L X-52; Inhibitor korosi; Ekstrak tembakau; Laju korosi; Polarisasi; Steel of API 5L X-52; Corrosion inhibitor; Tobacco extracts; Rate of corrosion; Polarization Steel

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