Sifat Korosi Dari Material Berbasis Nb yang Mengandung 24% Berat Sn Pada Berbagai Konsentrasi Natrium Klorida [Corrosion Behavior Of Nb-Base Material Containing 24wt% Sn At Various Sodium Chloride Concentrations]

Gadang Priyotomo

Abstract

Sifat korosi pada material berbasis Nb yang berisi 24% berat Sn yang terdiri dari fasa Nb3Sn dan NbSn2 telah diinvestigasi dengan menggunakan pengujian polarisasi, potensiostatik dan  metode analisis permukaan (SEM dan EDS) di dalam larutan netral NaCl. Pelarutan terseleksi pada fasa NbSn2  terjadi dengan konsentrasi rendah pada Nb dibandingkan dengan fasa Nb3Sn.  Melalui kurva polarisasi, rapat arus korosi dan laju korosi pada material meningkat dengan peningkatan konsentrasi klorida.   Pada daerah pasif, pelarutan terseleksi tidak terjadi pada dua fasa yang ada, namun pelarutan tersebut terjadi di daerah transpasif. Peningkatan konsentrasi klorida memberikan efek mengganggu terhadap ketahanan korosi pada material. Hasil yang didapat juga menjelaskan efek galvanik antara fasa-fasa yang menyebabkan kelarutan terseleksi pada fasa NbSn2.

 

Abstract

The corrosion behavior of Nb-base material containing 24wt% Snthat are consisted of Nb3Sn and NbSn2
phases, has been investigated using polarization test, potentiostatic test and surface analytical method (SEM;
scanning electron microscope and EDS; Energy Dispersive Spectroscopy) in neutral NaClsolutions. It was
found that the preferential dissolution of NbSn2 phase with a lower Nb concentration compared to Nb3Sn
phase. From polarization curves, the corrosion current density and corrosion rate of the material increase
with the increase of chloride concentration. In passive region, there is no preferential dissolution in both the
phases, whereas the preferential dissolution of NbSn2 takes place in transpassive region. The increase of
chloride concentration has detrimental effect in the corrosion resistance of the material. The results obtained
were also explained the galvanic effect between the phases generating for the preferential dissolution of
NbSn2 phase.

Keywords

Kelarutan terseleksi; Korosi; Konsentrasi klorida; Uji polarisasi; Preferential dissolution; Corrosion; Chloride concentration; Polarization test

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